Section 1: Identification
Product Name: GreenClean® PRO
Product Type/Description: Algaecide/fungicide
Recommended Use/ Use Restrictions: Pesticide, water treatment,
oxidizing agent. It is a violation of federal law to use this product
in a manner inconsistent with its labeling
Other Means of Identification: Sodium Carbonate Peroxyhydrate,
Sodium Percarbonate, SPC
EPA Registration Number: 70299-15
Manufacturer: BioSafe Systems LLC
22 Meadow Street, East Hartford, CT 06108
Telephone Number: (888-273-3088)
Emergency Number: 800-424-9300 (CHEMTREC)
Section 2: Hazard Identification
GHS Classification:
Oxidizing Solid: Category 2
Acute Toxicity (Oral): Category 4
Eye Damage Category 1
Hazard Statements:
May intensify fire, oxidizer.
Harmful if swallowed.
Causes serious eye damage.
Signal Word: DANGER
Precautionary Statements:
General:
If medical advice is needed, have product container or label at hand
Keep out of reach of children
Read label before use.
Prevention:
Keep away from heat, sparks or open flames, no smoking
Store away from combustible materials
Take any precautions to avoid mixing with combustibles
Wear protective gloves, clothing, eye protection, face protection
Response:
IF SWALLOWED : Call a POISON ENTER or doctor/physician if
you are unwell
IF ON SKIN: Wash with plenty of water
IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue
Rinsing.
Immediately call a POISON CENTER/doctor
Disposal
Dispose of contents/container in accordance with local/regional/national/international regulations
other Information:
NFPA Rating: Health – 2 Flammability – 0 Reactivity – 1 Special –OXY
HMIS Rating: Health – 2 Flammability – 0 Reactivity – 1 PPE – Required
Section 3: Composition/Information on Ingredients
Components:
Sodium carbonate peroxyhydrate
Identifiers:
15630-89-4
% Concentration by Weight:
85.0%
Section 4: First-aid Measures
Eye Contact:
Hold eye open and rinse slowly and gently with water for 15 – 20 minutes. Remove contact lenses, if present, after the first 5
minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
Skin Contact:
Remove contaminated clothing and wash affected area with soap and warm, running water. If irritation persists, consult a
physician.
Ingestion
Consult with physician in all cases. Rinse mouth and administer fresh water, do not induce vomiting.
Inhalation:
Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by
mouth-to-mouth, if possible. Call a poison control center or doctor for treatment advice
Note to Physician:
Oxidizer, corrosive. Probable mucosal damage may contraindicate the use of gastric lavage.
Section 5: Fire-fighting Measures
Suitable Extinguishing Media:
Water, fire extinguisher media
Unsuitable Extinguishing Media:
None known
Combustion Products:
CO, CO2, O2
Unusual Fire and Explosion Hazards:
Oxidizing substance, exothermic decomposition releases oxygen, may support combustion.
Protective Equipment for
Firefighters:
Personnel should wear normal protective gear (full bunker gear) and breathing apparatus.
Section 6: Accidental Release Measures
Personal Precautions:
Work to prevent dust cloud formation. No open flames in area. Wear protective clothing and glasses.
Emergency Procedures
Keep away from incompatible products, sweep up to prevent slipping hazard
Environmental Precautions
Avoid release to the environment, contain released material
Methods and Material for
Containment and Cleaning up
Place spilled material into a suitable container using protective clothing, avoid dust cloud formation. After
removing material, clean affected area/surfaces with an excess of water.
Section 7: Handling and Storage
Handling:
Avoid creating dust. Keep away from open flames/heat. Keep container closed tightly when not in use. Wear safe clothing
and eye protection.
Storage:
Keep container closed tightly in storage. Store in a dry location and out of direct sunlight. Store separately from
incompatible materials.
Incompatible Materials:
Oxidizing agents (strong acids/bases), metals, organic materials, water/moisture.
Section 8: Exposure Controls/Personal Protection
Engineering Controls
Avoid raising dust, Keep away from flames/heat. General room ventilation is required,
maintain adequate ventilation
Personal Protection
Equipment
Respiratory
For most conditions, no respiratory protection should be needed. For excessive dust
condition: dust mask with filter type P2
Eye/Face Protection
Face shield, in case of dust production; protective goggles
Hands
Protective gloves – chemical resistant
Skin/Body
Protective clothing – dust proof clothing
General Hygienic Practices
Wash with soap and water after use. Wash chemical from skin as soon as possible, especially
before eating or smoking
Section 9: Physical and Chemical Properties
Appearance: White granular solid
Odor: None
pH: 3% solution approx. 10.5
Melting Point: N/A
Freezing Point: N/A
Boiling Point: N/A
Flash Point: N/A (inorganic)
Flammability: Non combustible
Flammable Limits: N/A
Vapor Pressure: N/A
Bulk Density: 0.9 – 1.2 g/cm3
Solubility (ies): 140g/L at 20 C
Partition Coefficient n- octanol/water:
N/A
Auto-ignition Temperature:
N/A
Decomposition Temperature: >55°C
Section 10: Stability and Reactivity
Stability:
Stable under normal conditions
Conditions to Avoid
Heat/heat sources and moisture
Incompatible materials
Water, strong acids/bases, metals, organic materials, reducing agents.
Hazardous Decomposition
Products
Oxidation can increase fire risk. Decomposition releases CO2 and O2
Section 11: Toxicological Information
Acute Toxicological Date:
Oral Toxicity: LD50 rat, male/female 1034
mg/kg
Dermal Toxicity: LD50: rabbit, male/female
>2000 mg/kg
Inhalation Toxicity: LD 50: 1 hour, rat > 4580
mg/m3
Skin irritation: slight irritant
Eye irritation: Highly irritating
Likely Routes of Exposure:
Symptoms and effects:
Acute Effects
Eye Contact
Risk of severe damage
Skin Contact
Slight irritation
Inhalation
May cause respiratory track irritation
Ingestion
Harmful if swallowed
Section 12: Ecological Information
Ecotoxicity
Fishes, Pimephales promelas, LC50, 71 mg/l, Daphnia pulex EC50 4.9mg/l 48 hrs.
Persistence and degradability
Bio-degrades rapidly and naturally into water and oxygen
Bioaccumulation potential
None
Mobility is Soil
Low potential for adsorption in soil
Other adverse effects
Danger to environment is limited – due to product properties
Section 13: Disposal Considerations
Waste From Residues and Unused Product
Dispose of waste in accordance with local and/or federal, state and local regulations
Contaminated Container Disposal
Non-refillable container. Do not reuse or refill this container. Rinse empty containers with clean
water. Clean and empty containers are to be recycled or placed in the trash.
Section 14: Transport Information
UN Number
UN Proper Shipping Name
Hazard Class
(Subsidiary)
Label (Subsidiary)
Packing
Group
Marine
Pollutant
US DOT
3378
Sodium Carbonate Peroxyhydrate
5.1
Oxidizer
II
No
Special Precautions: Shipping Container: UN Certified vented
Section 15: Regulatory Information
TSCA Inventory List: In compliance with inventory
US EPA CERCLA Hazardous Substances: not regulated
SARA Title III Section 302/303 Extremely Hazardous
Substance: not listed
EHS RQ: N/A
TPQ: N/A
SARA Title III Sec. 311/312:
Hazard category: Fire hazard
TPQ: N/A
US. EPA EPCRA Section 313 listed: not listed
Threshold quantity (processed or
manufactured): N/A
Threshold quantity (otherwise
used): N/A
Canadian WHIMIS
Classification
C, D2B
California Prop 65
This product does not contain any chemicals known to the State of California to cause cancer, birth, or
any other reproductive defects.
EPA
This product is a registered Pesticide with the United States Environmental Protection Agency and is subject to EPA labeling requirements under the Federal Insecticide, Fungicide, and Rodenticide Act (“FIFRA”). These requirements may differ from the classification criteria and hazard information required for a safety data sheet under the Global Harmonized Systems (GHS), and for workplace labels of non-pesticide chemicals. It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Always refer to product label for further precautionary information and use directions.
Section 16: Other Information
To the extent of our knowledge, the information herein is accurate as of the date of this document. However, neither BioSafe Systems nor any of it’s affiliates make any warranty, expressed or implied, or accept any liability in connection with the information or its use. The information is for use by technically skilled persons at their own discretions and risk. This is not a license or a patent. The user alone must finally determine suitability of any information or material for any contemplated use, the manner or use and whether any patents are infringed.
For additional information on GreenClean PRO call us toll-free at 1.888.273.3088 or visit www.biosafesystems.com.
©2014 Copyright BioSafe Systems, LLC. ®GreenClean PRO is a registered trademark of BioSafe Systems, LLC. Always read and follow label
directions.
Copied and Recorded Here Date: 2/5/16 Revision Number: 01